Method for production of sulfide group-containing thiol compound
A method for the production of a sulfide group-containing thiol compound which comprises causing alkylene sulfide to react with a thiol compound in the presence of at least one basic catalyst selected from the group consisting of basic ion-exchange resins, quaternary ammonium compounds and alkyl pyridinium compounds, thereby inducing the ring-opening addition of the alkylene sulfide to the thiol compound. Further, a method for the production of a sulfide group-containing mercaptocarboxylic ester which comprises causing an alkylene sulfide to react with a mercaptocarboxylic ester.
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(2008/06/13)
EXCHANGE REACTIONS OF DIAZIRINES: 3-X-3-METHYLDIAZIRINES AND DERIVED CARBENES
3-Bromo-3-methyldiazirine readily undergoes exchange reactions with F(1-), MeO(1-), CN(1-), or N3(1-).New carbene precursors can thus be prepared.
Moss, Robert A.,Fedorynski, Michal,Kmiecik-Lawrynowicz, Grazyna,Terpinski, Jacek
p. 2707 - 2710
(2007/10/02)
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