Synthesis and Properties of Substituted 1-Alkoxy-2-azaallenium Salts
12 novel substituted 1-alkoxy-2-azaallenium salts 1 have been prepared by reaction of the N-methyleneamides 3 with trialkyloxonium salts 4.During the alkylation reaction of the N-benzylideneamides 3m, n a formal disproportionation takes place to yield hig
Kupfer, Rainer,Wuerthwein, Ernst-Ulrich
p. 857 - 871
(2007/10/02)
N-Acyl-α-imino Acid Derivatives, II. - Synthesis of N-Acylimines of Methyl Phenylglyoxylate
The title compounds 8 are obtainable via treatment of phenylglycine methyl ester (2) with tert-butyl hypochlorite or by direct dehydrogenation of the N-acylphenylglycine ester 6 with N-bromosuccinimide.
Koeppen, Juergen,Matthies, Dieter,Schweim, Harald
p. 2383 - 2389
(2007/10/02)
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