- Synthesis of benzo[c] and naphtho[c]heterocycle diesters and dinitriles via homoelongation
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(Chemical Equation Presented) Syntheses of benzo[c] and naphtho[c]heterocycle diesters and dinitriles were achieved via our newly developed iterative elongation protocol. The photophysical and electrochemical properties of these conjugated systems are explored.
- Hsu, Dong-Tsou,Lin, Chih-Hsiu
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supporting information; experimental part
p. 9180 - 9187
(2010/03/02)
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- Barium Ferrate Monohydrate BaFeO4.H2O, a Useful Oxidant for the Oxidation of Organic Compounds under Aprotic Conditions
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Preparation of barium ferrate monohydrate with a slight modification is described.It is shown that this reagent is capable of oxidizing different organic compounds and could be used as a versatile reagent in organic synthesis.Primary and secondary alcohols are converted to their carbonyl compounds, α-hydroxy ketones to their diketones, and hydroquinones to their quinones.Aromatic amines are converted to their azo compounds, benzylamine to benzaldehyde, phenylhydrazones and oximes to their carbonyl compounds.Thiols are also converted to their disulfides in high yields.This reagent seems to be a non-toxic and a non-pollutant compound.
- Firouzabadi, Habib,Mohajer, Daryoush,Entezari-Moghadam, Mohsen
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p. 2185 - 2190
(2007/10/02)
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- BARIUM FERRATE NONOHYDRATE BaFeO4, H2O, A VERSATILE REAGENT FOR THE OXIDATION OF ORGANIC COMPOUNDS UNDER APROTIC CONDITION
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Barium ferrate monohydrate which seems to be a safe and a non-pollutant compound, is an easily prepared, a quite stable and a cheap oxidant.Its uses as a versatile oxidizing agent of organic compounds are described.
- Firouzabadi, H.,Mohajer, D.,Entezari-Moghaddam, M.
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p. 723 - 732
(2007/10/02)
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- SILVER FERRATE Ag2FeO4, AN EFFICIENT AND SELECTIVE OXIDIZING AGENT FOR THE OXIDATION OF BENZYLIC AND ALLYLIC ALCOHOLS TO THEIR CORRESPONDING CARBONYL COMPOUNDS IN APROTIC ORGANIC SOLVENTS
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The title compound has been used for the selective and efficient oxidation of benzylic and allylic alcohols in benzene.
- Firouzabadi, H.,Mohajer, D.,Moghaddam, M. Entezari
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p. 211 - 224
(2007/10/02)
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- CERIC TRIETHYLAMMONIUM NITRATE (NO3)6; AN EFFICIENT OXIDANT FOR THE OXIDATION OF BENZYLIC ALCOHOLS AND α-HYDROXY KETONES TO THEIR CORRESPONDING CARBONYL COMPOUNDS UNDER MILD CONDITIONS
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Ceric triethylammonium nitrate is prepared and used for the oxidation of benzylic alcohols, and α-hydroxy ketones to their corresponding carbonyl compounds in methylene chloride with high yields.
- Firouzabadi, H.,Iranpoor, N.
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p. 1143 - 1148
(2007/10/02)
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- BARIUM MANGANATE. A VERSATILE OXIDANT IN ORGANIC SYNTHESIS.
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Preparation of barium manganate in large-scale is discussed. It is also shown that this reagent is capable of oxidizing organic substrates, converting alcohols to their corresponding carbonyl compounds, aromatic amines to their corresponding azo compounds, hydroquinone to p-benzoquinone, benzylamine to benzaldehyde, and triphenylphosphine to its oxide in good yields. Saturated hydrocarbons, unsaturated hydrocarbons, unsaturated ketones, and saturated amines are not affected by this reagent in a reasonable reaction time.
- Firouzabadi,Mostafavipoor
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p. 914 - 917
(2007/10/02)
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- BISPYRIDINESILVER PERMANGANATEMnO4: AN EFFICIENT OXIDIZING REAGENT FOR ORGANIC SUBSTRATES
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Bispyridinesilver permanganate is an easily prepared crystalline relatively stable compound, soluble in organic solvents; its uses as an oxidizing agent of organic compounds in benzene are described.
- Firouzabadi, H.,Vessal, B.,Naderi, M.
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p. 1847 - 1850
(2007/10/02)
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