The reaction of the title compound with dichloroacetic acid esters in the presence of butyllithium gave esters of 3-thienyl-3-hydroxy-2,2-dichloropropionic acid. Keywords: dichloroacetate, dichlorohydrin.
Mamedov, V. A.,Valeeva, V. N.,Antokhina, L. A.,Nuretdinov, I. A.
Process for producing dichloroacetoxypropane and derivatives thereof
A process for producing dichloroacetoxypropane comprising reacting allyl acetate with chlorine in a gaseous phase in the presence of a catalyst comprising an element of Group 16 of the long-form Periodic Table or in the absence of a catalyst. The dichloroacetoxypropane obtained may be converted to dichloropropanol and epichlorohydrin.
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(2008/06/13)
Process for producing dichloroacetoxypropane and derivatives thereof
A process for producing dichloroacetoxypropane comprising reacting allyl acetate with chlorine in a gaseous phase in the presence of a catalyst. The dichloroacetoxypropane obtained may be converted to dichloropropanol and epichlorohydrin.
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(2008/06/13)
PREPARATION OF ALIPHATIC ESTERS OF DICHLOROACETIC ACID FROM PENTACHLOROACETONE
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Khaskin, I. G.,Migaichuk, I. V.
p. 896 - 899
(2007/10/02)
REACTIVITY OF CHLOROSUBSTITUTED α-EPOXIDES AND SYNTHESES UNDER THESE COMPOUNDS
The reactivity of chloroepoxyethanes in reactions with nucleophiles and electrophiles increases sharply with the accumulation of chlorine atoms on the epoxide ring.The reaction rate correlates with the nucleophile strength.Reactions with strong nucleophiles proceed through epoxide isomerization and lead to chloroacetic acid derivatives.Addition to the epoxide ring is found only for several weak nucleophiles.
Voronina, T. A.,Fomina, N. V.,Suminov, S. I.
p. 1059 - 1063
(2007/10/02)
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