cas 37763-43-2, 1-bromo-2-(bromomethyl)naphthalene | Articles data ｜lookchem

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37763-43-2

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Selective benzylic bromination of 2-methylnaphthalene
A practical synthesis of 2-(bromomethyl)naphthalene (1) by selective benzylic bromination of 2-methylnaphthalene (2) with bromine in heptane in the presence of lanthanum acetate hydrate is described.
Waykole, Liladhar,Prashad, Mahavir,Palermo, Stephen,Repic, Oljan,Blacklock, Thomas J.
p. 2159 - 2163
(2007/10/03)

The easy preparation of many benzylic bromides using molecular bromine as a halogenating in the presence of catalytic amounts of lanthanum tri-acetate
Many benzylic brominations were easily achieved by molecular bromine in CCl4 in presence of 1 percent of La (OAc)3 and a standard room lighting lamp.The selectivity is excellent except for certain electron-rich systems (p-methylaniline, p-cresol).
Ouertani, Mohsen,Girard, Pierre,Kagan, Henry B.
p. 327 - 328
(2007/10/02)

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Chemical Properties

Melting Point: 108oC
Boiling Point: 363.2°C at 760 mmHg
Flash Point:202.5°C
Density: 1.772g/cm³
Vapor Pressure: 3.82E-05mmHg at 25°C
BRN: 1943405
PSA: 0.00000
LogP: 4.49720

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