Synthesis of tert-alkylperoxy-substituted derivatives of 2-propanol, dioxolane, and thiirane
Treatment of tert-alkyl-2-oxiranylmethyl peroxides with compounds containing an active hydrogen, with ketones, chlorosilanes, and potassium thiocyanate furnished a series of functionally-substituted dialkyl peroxides. 2005 Pleiades Publishing, Inc.
Elagin,Mizyuk,Kobrin,Vlyazlo
p. 1666 - 1670
(2007/10/03)
Thermodynamic Properties of Certain Hydroperoxides
The enthalpies of formation of t-butylperoxymethanol (CH3)3COOCH2OH (I), 1-t-butylperoxyethanol (CH3)COOCH2CH2OH (II), 1-t-pentylperoxyethanol C2H5(CH3)2COOCH2CH2OH (III), and 1-t-butylperoxypropane-2,3-diol (CH3)3COOCH2CHOHCH2OH (IV) have been determined by calorimetry.The vapour pressures of these substances have been measured by the effusion method in the temperature range 290-320 K.The energies of certain bonds and the enthalpies of formation of some of the biradicals have been calculated.
Van-Chin-Syan, Yu. Ya.,Kachurina, N. S.,Petrovskaya, G. A.,Chuchmarev, S. K.
p. 1751 - 1752
(2007/10/02)
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