Fluoride-mediated selective cross-coupling reactions of alkyl halides and trimethyl(perfluoroalkyl)silanes, Me3SiRf (Rf = CF3, C2F5) in the absence of any catalysts
A temperature range of -18 °C to room temperature was found to be effective for selective fluoride-mediated cross-coupling reactions of trimethyl(perfluoroalkyl)silanes, Me3SiCF3 and Me3SiC2F5, and alkyl halides, RX (X = Br, I) in the absence of any catalyst.
Tyrra, Wieland,Naumann, Dieter,Quadt, Silke,Buslei, Sigrid,Yagupolskii, Yurii L.,Kremlev, Mikhail M.