3-Trimethylsilylcycloalkylidenes. γ-Silyl vs γ-Hydrogen Migration to Carbene Centers
A series of γ-trimethylsilyl-substituted carbenes have been studied experimentally and by computational methods. In an acyclic system, 1,3-trimethylsilyl migration successfully competes with 1,3-hydrogen migration to the carbene center. The behavior of cy
Creary, Xavier
p. 11378 - 11387
(2015/12/01)
γ-Silicon Stabilization of Carbonium Ions in Solvolysis. 1. Solvolysis of cis- and trans-3-(Trimethylsilyl)cyclohexyl p-Bromobenzenesulfonates
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Shiner, V. J.,Ensinger, Mark W.
p. 842 - 844
(2007/10/02)
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