Intramolecular Cyclization Products from Alkanolamines and Epichlorohydrin
Tetriary (2-hydroxyethyl)dialkylamines reacted with epichlorohydrin to form mixtures containing equal amounts of 2-(hydroxymethyl)-4,4-dialkylmorpholinium chlorides and perhydro-6-hydroxy-4,4-dialkyl-1,4-oxazepinium chlorides.Secondary (2-hydroxyethyl)alkylamines gave a 9:1 ratio of the corresponding bases in agreement with the prediction of Baldwin's rules.
Buriks, Rudy S.,Lovett, Eva G.
p. 5247 - 5254
(2007/10/02)
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