- Role of Charge-Transfer Interactions in Photoreactions. 6. Photoinduced Electron Transfer and Trans -> Cis Isomerization for Styrylphenanthrene-Amine Systems in Acetonitrile
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The decay pathways of the lowest excited singlet state (S1) of trans-n-styrylphenanthrenes (n-StPh, with the location on phenanthrene n = 1, 2, 3, 4, and 9) were studied in acetonitrile at room temperature.Fluorescence lifetimes (τF)
- Aloisi, Gian Gaetano,Elisei, Fausto,Goerner, Helmut
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- ROLE OF CHARGE-TRANSFER INTERACTIONS IN PHOTOREACTIONS. VIII. FLUORESCENCE QUENCHING AND INDUCTION OF INTERSYSTEM CROSSING AND PHOTOISOMERIZATION BY INORGANIC ANIONS
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The relevance of intersystem crossing catalysis in the fluorescence quenching of n-styrylphenanthrenes (n-StPh, with n = 1, 2, 3, 9) by iodide, thiocyanate and bromide anions has been investigated.Quenching rate constants (kq) were found to dec
- Aloisi, Gian Gaetano,Elisei, Fausto,Latterini, Loredana,Galiazzo, Guido
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p. 181 - 186
(2007/10/02)
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- Role of Charge-Transfer Interactions in Photoreactions. 5. Photochemical Behavior of Exciplexes of trans-Styrylphenanthrenes and Amines
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The charge-transfer interactions between the five trans-n-styrylphenanthrene isomers (t-n-StPh, with n = 1, 2, 3, 4, and 9) and amines (tributylamine (TBA), diethylaniline (DEA), and 4-bromodimethylaniline (BrDMA)) have been studied in n-hexane by measuri
- Aloisi, G. G.,Elisei, F.
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p. 5813 - 5818
(2007/10/02)
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- Photophysical and Theoretical Studies of Photoisomerism and Rotamerism of trans-Styrylphenanthrenes
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The photophysical and photochemical properties and the ground-state conformational equilibrium of trans-n-styrylphenanthrene (n-StPh, with n = 1, 2, 3, 4, 9) have been studied in inert solvents.The kinetic parameters of the competitive radiative and react
- Bartocci, G.,Masetti, F.,Mazzucato, U.,Spalletti, A.,Baraldi, I.,Momicchioli, F.
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p. 4733 - 4743
(2007/10/02)
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- trans --> cis PHOTOISOMERIZATION AND LUMINESCENCE OF THE FIVE ISOMERIC n-STYRYLPHENANTHRENES
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The five isomers of trans-n-styrylphenanthrene (n-StPh, with n = 1, 2, 3, 4, 9) have been prepared by standard procedures.The 4-StPh, not described in the literature, has been spectrally and photochemically characterized.The fluorescence and trans --> cis
- Galiazzo, Guido,Spalletti, Anna,Bartocci, Giampiero,Aloisi, Gian Gaetano
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p. 705 - 708
(2007/10/02)
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