Photo-Induced Dihydroxylation of Alkenes with Diacetyl, Oxygen, and Water
Herein reported is a photo-induced production of vicinal diols from alkenes under mild reaction conditions. The present dihydroxylation method using diacetyl (= butane-2,3-dione), oxygen, and water dispenses with toxic reagents and intractable waste generation.
A series of 1,1 -disubstituted taurines was synthesized expeditiously from ketones via the Corey-Chaykovsky epoxidation with dimethylsulfonium methylide, episulfidation with potassium sulfocyanate, ring-opening reaction with ammonia in the presence of sil
Huang, Jiaxing,Du, Da-Ming,Xu, Jiaxi
p. 315 - 319
(2007/10/03)
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