A new alternative to Stryker's reagent in hydrosilylation: Synthesis, structure, and reactivity of a well-defined carbene-copper(II) acetate complex
A new, air stable and well-defined carbene-copper(II) complex has been prepared, which is an efficient precatalyst for the 1,2- and 1,4-reduction of carbonyl compounds under hydrosilylation conditions. The Royal Society of Chemistry 2005.
Yun, Jaesook,Kim, Daesung,Yun, Hoseop
p. 5181 - 5183
(2007/10/03)
Highly efficient conjugate reduction of α,β-unsaturated nitriles catalyzed by copper/xanthene-type bisphosphine complexes
α,β-Unsaturated nitriles are chemoselectively reduced to the corresponding saturated nitriles in high yields using a copper-DPEphos or Xantphos complex as catalyst in the presence of polymethylhydrosiloxane (PMHS) as the stoichiometric reducing agent and t-butanol as additive. The Royal Society of Chemistry 2005.
Kim, Daesung,Park, Bu-Mahn,Yun, Jaesook
p. 1755 - 1757
(2007/10/03)
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