cas 42866-92-2, Benzene, 1-(2,2-dimethoxyethyl)-4-methoxy-

Articles about 42866-92-2Total 6 be found

Lewis Base Catalyzed Dioxygenation of Olefins with Hypervalent Iodine Reagents
1,2-Diols are extremely useful building blocks in organic synthesis. Hypervalent iodine reagents are useful for the vicinal dihydroxylation of olefins to give 1,2-diols under metal-free conditions, but strongly acidic promoters are often required. Herein, we report a catalytic vicinal dioxygenation of olefins with hypervalent iodine reagents using Lewis bases as catalysts. The conditions are mild and compatible with various functional groups.
Pan, Liangkun,Ke, Zhihai,Yeung, Ying-Yeung
supporting information
p. 8174 - 8178
(2021/10/25)

Two-way homologation of aliphatic aldehydes: Both one-carbon shortening and lengthening via the same intermediate
Aliphatic aldehydes can be homologated to both one-carbon shorter and one-carbon longer homologous carbonyl compounds through the 2–4 steps of reactions via the same intermediates, β,γ-unsaturated α-nitrosulfones, prepared from the proline-catalyzed sequential reactions of several aliphatic aldehydes with phenylsulfonylnitromethane. While the oxidative cleavage of the key intermediates gave one-carbon less homologous carbonyl compounds, the reduction of the same key intermediates followed by an oxidation produced one-carbon more homologous carbonyl compounds.
Yoo, Jae Won,Seo, Youngran,Park, Jong Beom,Kim, Young Gyu
(2020/01/13)

Highly Selective One-Pot Synthesis of Polysubstituted Isoflavanes using Styryl Ethers and Electron-Withdrawing ortho -Quinone Methides Generated in Situ
A highly selective one-pot synthesis of polysubstituted isoflavanes has been developed. The reaction proceeds through the cycloaddition of methyl styryl ethers, derived from phenylacetaldehyde dimethyl acetals under acidic conditions, with electron-withdrawing ortho -quinone methides generated in situ. When phenylacetaldehyde dimethyl acetals were reacted with salicylaldehydes, the reaction proceeded smoothly to afford the corresponding isoflavanes stereoselectively in high yields and with excellent regioselectivities. The present reaction provides versatile access to functionalized isoflavanes, and constitutes a useful tool for the synthesis of biologically active molecules.
Tanaka, Kenta,Kishimoto, Mami,Ohtsuka, Naoya,Iwama, Yoshinori,Wada, Hiroki,Hoshino, Yujiro,Honda, Kiyoshi
supporting information
p. 189 - 192
(2019/01/14)

Hypoiodous acid-catalyzed regioselective geminal addition of methanol to vinylarenes: synthesis of anti-Markovnikov methyl acetals
A novel metal-free, catalytic geminal dimethoxylation of vinylarenes based on in situ generated HOI species from iodide salt and oxone is reported. The preliminary mechanistic investigations suggest that the key factor for achieving the anti-Markovnikov regioselectivity is the semipinacol rearrangement of an iodo functionalized intermediate, which is confirmed by an isotope labeling experiment. In addition, the reaction involves the de-iodination of a co-iodo intermediate via its oxidation to hypervalent iodine species rather than a common iodide abstraction by electrophiles. The HRESI-MS studies support the conversion of monovalent iodine containing intermediates to trivalent iodine intermediates during the catalytic conversion of aromatic alkenes into the corresponding terminal acetals.
Peraka, Swamy,Mameda, Naresh,Marri, Mahender Reddy,Kodumuri, Srujana,Chevella, Durgaiah,Sripadi, Prabhakar,Nama, Narender
p. 73732 - 73736
(2015/09/15)

A generalized approach for iron catalyzed chemo- and regioselective formation of anti-Markovnikov acetals from styrene derivatives
Fe(BF4)2·6H2O in the presence of pyridine-2,6-dicarboxylic acid and PhI(OAc)2 can efficiently catalyze the formation of chemoselective dialkyl acetals from styrene derivatives with anti-Markovnikov regioselectivity in good to high yields under mild and benign reaction conditions.
Chowdhury, Abhishek Dutta,Lahiri, Goutam Kumar
supporting information; experimental part
p. 3448 - 3450
(2012/05/20)

Studies of enzyme-mediated reactions. Part 12. Stereochemical course of the decarboxylation of (2S)-tyrosine to tyramine by microbial, mammalian, and plant systems.
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Battersby,Chrystal,Staunton
p. 31 - 42
(2007/10/02)