Catalytic C-F bond activation of hexafluoropropene by rhodium: Formation of (3,3,3-trifluoropropyl)silanes
A clean break: The novel catalytic conversion of hexafluoropropene into (3,3,3-trifluoropropyl)silanes by C-F activation has been developed (see scheme). The reactions are catalyzed by the rhodium complex [Rh{(Z)-CF= CF(CF3)}(PEt3)3], proceed at room temperature, and are highly selective. (Chemical Equation Presented).