- REACTION OF ORGANIC COMPOUNDS WITH SF4-HF-HALOGENATING SYSTEM VII. REACTIONS OF OLEFINS WITH THE SF4-HF-Cl2(Br2) SYSTEM
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Under the influence of the SF4-HF-Cl2(Br2) system halogen-containing olefins undergo conjugate halogenofluorination.It was shown for the case of (Z)- and (E)- 1,2-dichloroethenes that these reactions take place anti-stereospecifically through the formation of the bromonium ions.The accumulation of chlorine atoms in the olefin molecule hinders electrophilic addition of stoichiometric equivalents of ClF and BrF at the double bond.The SF4-HF-Br2 system is an effective agent for substitutive fluorination of organic compounds containing bromine.Only the bromine atoms situated at the secondary carbon atom are substituted by fluorine.
- Kunshenko, B. V.,Mokhamed, Nagib Mukhtar,Omarov, V. O.,Muratov, N. N.,Yagupol'skii, L. M.
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p. 511 - 518
(2007/10/02)
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- Process for producing hydrocarbon fluoride
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A process for producing a hydrocarbon fluoride at a high selectivity with minimum formation of by-products is disclosed, which comprises reacting a hydrogen-containing hydrocarbon halide with anhydrous hydrogen fluoride in a liquid phase in the presence of a reaction product of (i) at least one of (a) an oxygen-containing compound selected from the group consisting of H2 O, H2 O2 and an oxygen-containing organic compound, and (b) a nitrogen-containing compound selected from the group consisting of NH3 and a nitrogen-containing organic compound, (ii) a tin compound selected from the group consisting of a stannic halide, a stannic oxyhalide and an organotin compound, and (iii) anhydrous hydrogen fluoride.
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