cas 454-41-1, DL-METHIONINE SULFOXIDE | Articles data ｜lookchem

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454-41-1

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Oxidation by chlorine dioxide of methionine and cysteine derivatives to sulfoxides
Methionine and cysteine derivatives were oxidized asymmetrically by chlorine dioxide to sulfinyl derivatives.
Loginova,Rubtsova,Kuchin
experimental part
p. 752 - 754
(2009/05/09)

A General Procedure for the Selective Oxidation of Sulfides to Sulfoxides by Nitric Acid: Tetrabromoaurate(III) Catalyst in a Biphasic System
Tetrabromoaurate(III) is an efficient catalyst for the oxidation of sulfides to sulfoxides by nitric acid in a biphasic system (nitromethane/water).The system is selective and can be applied to the oxidation of any type of dialkyl and alkyl aryl sulfide and also of diaryl sulfides activated by electron-releasing substituents.The nature of the active species has been investigated in relation to the mechanistic aspects.
Gasparrini, Francesco,Giovannoli, Mario,Misiti, Domenico,Natile, Giovanni,Palmieri, Gianni
p. 1323 - 1328
(2007/10/02)

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Chemical Properties

Melting Point: -240oC (dec.)
Density: 1.183 (estimate)
Refractive Index: 1.5216 (estimate)
PSA: 99.60000
LogP: 0.73290

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