REACTION OF VINYLOXYORGANOSILANES WITH HYDROGEN CHLORIDE
-
Lisovin, E. G.,Komarov, N. V.
p. 631 - 632
(2007/10/02)
MECHANISM OF OXIDATION OF ORGANOPOLYSILANES BY PEROXY ACIDS
-
Razuvaev, G. A.,Brevnova, T. N.,Semenov, V. V.,Kornev, A. N.,Lopatin, M. A.,et al.
p. 2010 - 2013
(2007/10/02)
SELECTIVITY IN THE REACTIONS OF ALKYLLITHIUM REAGENTS WITH α, ω-DICHLOROPERMETHYLSILOXANES
The reactions of 1,3-dichlorotetramethyldisiloxane and 1,5-dichlorohexamethyltrisiloxane with alkyllithium reagents have been studied.At low temperature (-78 deg C) only one of the two silicon-chlorine bonds of 1,3-dichlorotetramethyldisiloxane reacts readily with alkyllithium reagents.This permits the selective preparation of 1-alkyl-3-chlorotetramethyldisiloxanes or by hydrolysis 1-alkyl-3-hydroxytetramethyldisoloxanes.The silicon-chlorine bond of 1-alkyl-3-chlorotetramethyldisiloxanes reacts with alkyllithium reagents at higher temperatures (0 deg C).Both the silicon-chlorine bonds of 1,5-dichlorohexamethyltrisiloxane react competitively with alkyllithium reagents at -78 deg C.No cleavage of siloxane bonds by alkyllithium reagents is observed under these conditions.Spectral properties of a number of 1-alkyl-3-hydroxytetramethyldisiloxane and 1-alkyl-5-hydroxyhexamethyltrisoloxanes are reported.
Kazoura, Samih Amine,Weber, Wolliam P.
p. 149 - 156
(2007/10/02)
More Articles about upstream products of 4619-08-3