A concise synthesis of tetrahydroxy-LCB, α-galactosyl ceramide, and 1,4-dideoxy-1,4-imino-L-ribitol via D-allosamines as key building blocks
The total syntheses of tetrahydroxy-LCB 1, α-galactosyl ceramide 2, and 1,4-dideoxy-1,4-imino-L-ribitol 3 via D-allosamine derivatives as common synthons are described here.
Synthesis of D-ribo-C18-phytosphingosine from D-glucosamine via the D-allosamine derivatives as key intermediates
A straightforward synthesis of D-ribo-C18-phytosphingosine from D-glucosamine hydrochloride in ten steps in 18.4% overall yield via the D-allosamine derivatives as key intermediates is described here.