- Multi-branched thioether type episulfide compound, and preparation method and application thereof
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The invention provides a multi-branched thioether type episulfide compound, and a preparation method and an application thereof. The multi-branched thioether type episulfide compound is prepared by adopting a specific method, so the transparency, refractive index and heat resistance of an optimal material prepared from the multi-branched thioether type episulfide compound meet the requirements foroptical plastics on the market, the refractive index reaches 1.75 or above, and the optical material is a plastic lens material with excellent performances and wide application prospect.
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Paragraph 0074; 0077; 0078; 0083; 0085; 0086
(2020/02/29)
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- Preparation method of 2-2-dimercaptomethyl-1-3-propanedithiol
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The invention belongs to the field of synthesis of thiol compounds, and particularly relates to a preparation method of 2-2-dimercaptomethyl-1-3-propanedithiol, which comprises the following steps: mixing pentaerythritol, hydrochloric acid and thiourea, reacting, and adding an alkaline solution to obtain 2-2-dimercaptomethyl-1-3-propanedithiol. The preparation method of 2-2-dimercaptomethyl-1-3-propanedithiol has the advantages of high product sulfydryl content and high refractive index, and the obtained product can be used for preparing high refractive index lenses; the synthesis process is simple, raw materials are easily available, and product added value is high.
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Paragraph 0024; 0027-0038
(2020/05/01)
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- Molecular rods based on oligo-spiro-thioketals
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We report on an extension of the previously established concept of oligospiroketal (OSK) rods by replacing a part or all ketal moieties by thioketals leading to oligospirothioketal (OSTK) rods. In this way, some crucial problems arising from the reversible formation of ketals are circumvented. Furthermore, the stability of the rods toward hydrolysis is considerably improved. To successfully implement this concept, we first developed a number of new oligothiol building blocks and improved the synthetic accessibility of known oligothiols, respectively. Another advantage of thioacetals is that terephthalaldehyde (TAA) sleeves, which are too flexible in the case of acetals can be used in OSTK rods. The viability of the OSTK approach was demonstrated by the successful preparation of some OSTK rods with a length of some nanometers.
- Wessig,Gerngro?,Freyse,Bruhns,Przezdziak,Schilde,Kelling
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p. 1125 - 1136
(2016/02/19)
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- Synthesis and stereochemistry of some new spiro and polyspiro-1,3-dithiane derivatives
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The synthesis of new spiro and trispiro compounds with 2,4,8,10-tetrathiaspiro[5.5]undecane and 7,11,18,21-tetrathia[5.2.2.5.2.2]heneicosane units is reported. The structural analysis was carried out by NMR investigations and the X-ray single crystal mole
- Gaz, ?erban Andrei,Condamine, Eric,Bogdan, Niculina,Terec, Anamaria,Bogdan, Elena,Ramondenc, Yvan,Grosu, Ion
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p. 7295 - 7300
(2008/12/21)
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- Conformational analysis of spiro-bis-dithiepins: A peculiar case of axial chirality
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(Figure Presented) Spiro-bis-dithiepins are synthesized via dehydrative ring expansion in α-hydroxyalkyl spiro-bis-dithianes. Atypical of spiranes possessing axial chirality, the two most stable conformers of substituted spiro-bis-dithiepin have virtually
- Wade, Edmir O.,Valiulin, Roman A.,Ruybal, Leslie A.,Kutateladze, Andrei G.
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p. 5121 - 5124
(2007/10/03)
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- SYNTHESIS OF NEW MACROCYCLIC POLYTHIAETHER
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Synthesis of a new macrocyclic polythiaether (12) which is easily obtained in a good yield via 2,6-dithia-4-spiroheptane (6) is described.Several reactions of pentaerythrityl bromide (1) with nucleophiles and a few ring opening reactions of 6 with methyl iodide are also described.
- Fujihara, Hisashi,Imaoka, Koji,Furukawa, Naomichi,Oae, Shigeru
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p. 1701 - 1704
(2007/10/02)
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