HALOGENATION OF UNSATURATED ESTERS-II. ADDITION OF Cl2, BrCl AND Br2 TO METHYL ESTERS OF MONOCHLOROPROPENOIC ACIDS
The addition of chlorine, bromine chloride and bromine to methyl 2-chloropropenoate 1, methyl cis-3-chloropropenoate 2 and methyl trans-3-chloropropenoate 3 under ionic and radical conditions gave regioisomer mixtures.Both trans- and cis-addition of halogen species was observed, bromine preferentially adding to the non-halogenated carbon atom.
Pitkaenen, Maija,Korhonen, Ilpo O. O.
p. 3367 - 3372
(2007/10/02)
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