Synthesis of Photosensitive Poly(2,5-Norbornadien-7-yl Acrylate and Methacrylate)
2,5-Norbornadien-7-yl acrylate and methacrylate were synthesized by the esterification of 2,5-norbornadien-7-ol with acryloyl and methacryloyl chlorides, respectively.Polymerization of the monomers with AIBN provided vinyl polymers with pendant norbornadi
Catalysis of the thermal quadricyclane -> norbornadiene isomersation by mercury(II) halides
Quadricyclanes are rapidly isomerised to norbornadienes by Hg(II) halides under very mild conditions, corner-mercuration being assumed to be the essential step.With quadricyclane and 3-tert-butyl-quadricyclane, zero-order kinetics were found.
Rood, I. D. Ch.,Klumpp, G. W.
p. 303 - 304
(2007/10/02)
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