- Stereoselective Synthesis of Octadeacpolyenoic Esters as an Insecticide
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Octadecapolyenoic acid derivatives such as (+/-)-t-butyl coriolate, α-eleostearic acid, t-butyl punicate, and t-butyl (9Z,11E)-13-hydroxy-9,11-octadien-15-ynoate were synthesized starting from oleic acid with high stereoselectivity and their insecticidal
- Tsuboi, Sadao,Wu, Xue Han,Maeda, Seiji,Ono, Shinichiro,Kuroda, Akihisha,et al.
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p. 1103 - 1108
(2007/10/02)
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- STEREOSELECTIVE PREPARATION OF 1-CHLORO-(E,E)-1,3-DIENES. APPLICATION TO THE SYNTHESIS OF METHYL ELEOSTEARATE.
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The nickel (or palladium) catalyzed reaction of alkenylalanes with (E)-dichloroethylene affords 1-chloro-(E,E)-1,3-dienes under mild conditions.The syntheses of methyl α-eleostearate which is reported to be a feeding deterrent for the boll weevil on cotto
- Ratovelomanana, Victorin,Linstrumelle, Gerard
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p. 6001 - 6004
(2007/10/02)
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