Oxidation of partially protected carbohydrates at the nickel hydroxide electrode
Primary hydroxy groups in pyranoses are oxidized in excellent yields to the corresponding carboxylic acids. In furanose 3 the yield of acid is only moderate. Secondary hydroxy groups are inert, aside from lactols. The different reactivity of secondary and primary hydroxy groups allows the chemoselective oxidation of 8 and 10.
Schaefer, Hans J.,Schneider, Roy
p. 715 - 724
(2007/10/02)
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