- Synthesis and Absolute Configuration of the Naturally Occurring Cyano Glucoside Simmondsin
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The synthesis of the naturally occurring cyano glucoside simmondsin, 1, is reported.An optically active cyclitol, L-quebrachitol 2, was stereoselectively converted into the aglycone 19, which was condensed with D-glucose, follwed by deprotection to provid
- Chida, Noritaka,Yamada, Ken,Ogawa, Seiichiro
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p. 1131 - 1138
(2007/10/02)
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- Total Synthesis of Simmondsin
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The first total synthesis of the naturally occuring cyanoglucoside, simmondsin 1, starting from L-quebrachitol and D-glucose, is described, revealing the absolute configuration of this compound.
- Chida, Noritaka,Yamada, Ken,Ogawa, Seiichiro
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p. 588 - 590
(2007/10/02)
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