- Preparation of first examples of RFCCIF4 molecules. A study of the fluorination of selected 1-iodoalk-1-ynes with xenon difluoride/boron trifluoride
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First examples of alk-1-yn-1-yliodine(V) molecules, CF3CCIF 4 and C6F13CCIF4, were prepared by fluorination of the corresponding 1-iodoperfluoroalk-1-ynes with XeF2 in 1,1,1,3,3-pentafluoro
- Bardin, Vadim V.,Frohn, Hermann-Josef
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- Transformation of perfluorinated benzocycloalkenes and alkylbenzenes to their carbonyl derivatives under the action of CF3COOH/SbF5
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Perfluorinated benzocycloalkenes (benzocyclobutene, indan, tetralin), alkylbenzocycloalkenes and alkylbenzenes react with CF3COOH/SbF5 at 20-50 °C giving the corresponding carbonyl derivatives.
- Zonov, Yaroslav V.,Karpov, Victor M.,Platonov, Vyacheslav E.
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p. 1058 - 1064
(2008/02/10)
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- REACTION OF PERFLUORINATED METHYL- AND ALKENYLBENZENES WITH INORGANIC OXIDES IN THE PRESENCE OF ANTIMONY PENTAFLUORIDE
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A study was carried out on the reaction of perfluorinated toluene, m-xylene, p-xylene, mesitylene, and m-(1-propenyl)toluene with inorganic oxides in the presence of antimony pentafluoride.Depending on the reaction conditions, polyfluorinated acids resulting from the consecutive conversion of trifluoromethyl groups into carboxylic acid groups are obtained after hydrolysis of the reaction mixtures.
- Karpov, V. M.,Panteleev, I. V.,Platonov, V. E.
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p. 1932 - 1938
(2007/10/02)
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