- Stereocontrolled synthesis of the alkaloid (-)-actinidine
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The alkaloid (-)-actinidine of the iridane series was synthesized using intramolecular [3+2] dipolar cycloaddition of silyl nitronates, generated from (3R/S,6S)-2,6-dimethyl-3-nitro-8-phenylthioocta-1,7E-and -1,7Z-dienes. The key nitro compounds were obtained from (-)-(S)-citronellol.
- Stepanov,Lozanova,Veselovsky
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p. 2286 - 2291
(2007/10/03)
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- BIOMIMETIC SYNTHESIS OF (-)-DEOXYRHEXIFOLINE, (-)-TECOSTIDINE, AND (-)-ACTINIDINE
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The title monoterpene pyridine alkaloids were synthesized by transformations of the iridoid glycoside loganin.
- Ranarivelo, Yvonne,Hotellier, Francoise,Skaltsounis, Alexios-Leandros,Tillequin, Francois
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p. 1727 - 1731
(2007/10/02)
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