- ON THE REACTION OF 1-ETHOXYCARBONYL-1H-1,2-DIAZEPINE WITH MOLYBDENUM AND IRON CARBONYL COMPLEXES
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The reaction of 1-ethoxycarbonyl-1H-1,2-diazepine (3) with resulted in the N-N bond cleavage of the seven-membered ring to give dienaminocarboxaldehyde 4 and dienaminonitriles, 5 and 6.On the other hand, the reaction of 3 with or with afforded 4 and 6, or 2-(ethoxycarbonylamino)pyridine and N,N'-di(2-pyridyl)urea, in addition to -Fe(CO)3 complex.
- Nitta, Makoto,Miyano, Hiroyuki
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p. 1411 - 1418
(2007/10/02)
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