- Volatiles from the hypoxylaceous fungi Hypoxylon griseobrunneum and Hypoxylon macrocarpum
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The volatiles emitted by the ascomycetes Hypoxylon griseobrunneum and Hypoxylon macrocarpum (Hypoxylaceae, Xylariales) were collected by use of a closed-loop stripping apparatus (CLSA) and analysed by GC-MS. The main compound class of both species were polysubstituted benzene derivatives. Their structures could only be unambiguously determined by comparison to all isomers with different substitution patterns. The substitution pattern of the main compound from H. griseobrunneum, the new natural product 2,4,5-trimethylanisole, was explainable by a polyketide biosynthesis mechanism that was supported by a feeding experiment with (methyl-2H3)methionine.
- Rinkel, Jan,Babczyk, Alexander,Wang, Tao,Stadler, Marc,Dickschat, Jeroen S.
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p. 2974 - 2990
(2019/01/05)
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- Catalytic activity of a mordenite catalyst in alkylation of xylenols with methanol
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The catalytic activity of a palladium-containing mordenite catalyst in alkylation of 2,6-, 2,4-, 2,5-, 2,3-, 3,4-, and 3,5-xylenols with methanol was studied. The main and by-products of catalysis and the activity of the catalyst in synthesis of individual trimethylphenols were determined.
- Agaev,Madatzade
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p. 683 - 684
(2007/10/03)
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- Ortho-alkylation of phenol with methanol using Pb-Cr promoted magnesium oxide catalysts
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In this study, Pb-Cr promoted magnesium oxide catalysts were used to catalyze the ortho-alkylation of phenol in the presence of excess methanol. The Cr/MgO catalyst exhibited a high conversion of phenol and a relatively high selectivity for the ortho-alkylation of phenol. The catalytic activity and the stability of Cr/MgO were improved by the addition of a fairly small amount of Pb. The Pb-Cr/MgO catalyst showed specificity for the ortho-alkylation of phenol, which was proved by a series of phenol derivative reactions with methanol.
- Ke, Jyh-Harng,Zena, Jyh-Myng,Wang, Fey-Long
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p. 1407 - 1410
(2007/10/03)
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- ALKYLATION OF o-CRESOL BY METHANOL ON Ni-H MORDENITE.
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The authors report the main results of an investigation of the alkylation of o-cresol by methanol over a Ni-H-mordenite catalyst. Data is presented which shows the results of the investigation of the alkylation of o-cresol by methanol at different temperatures and per volume feed rates of the liquid raw material. The data also show the high activity of Ni-H mordenite in the heterogeneous alkylation of o-cresol by methanol by which 2,6- and 2,4-xylenols can be obtained in high yields. It is shown that the alkylation of o-cresol by methanol proceeds by a parallel-consecutive mechanism. Under the conditions used, the optimum yield of 2,6- and 2,4-xylenols is 74. 5-80. 5 and 10. 7-14. 8%, respectively, at a 30-36% conversion of phenol.
- Akhmedov,Agaev,Mamedov,Mamedov
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p. 1355 - 1357
(2007/10/02)
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- Polycyclic phenols, alcohols and ketones from phenols, cyclic alcohols and cyclic ketones using a nickel oxide/manganese oxide/magnesium oxide catalyst in presence of at least one of hydrogen and nitrogen
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At least one of a polycyclic phenol, a polycyclic alcohol and a polycyclic ketone is produced under hydrogenation conditions using a nickel oxide/manganese oxide/magnesium oxide catalyst by subjecting at least one of a monocyclic ketone, a monocyclic alcohol and a monocyclic phenol to said conditions and said catalyst.
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- Conversion of alkyl and aryl hydroxy compounds producing aldehyde, alcohol and ketone using manganese oxide/nickel oxide/magnesium oxide catalysts
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Alkyl and aryl hydroxy compounds are converted to aldehydes, alcohols, and ketones in the presence of hydrogen using a catalyst comprised of the oxides of manganese, nickel and magnesium.
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