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5287-45-6

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Exploiting the Synthetic Potential of Sesquiterpene Cyclases for Generating Unnatural Terpenoids
The substrate flexibility of eight purified sesquiterpene cyclases was evaluated using six new heteroatom-modified farnesyl pyrophosphates, and the formation of six new heteroatom-modified macrocyclic and tricyclic sesquiterpenoids is described. GC-O analysis revealed that tricyclic tetrahydrofuran exhibits an ethereal, peppery, and camphor-like olfactoric scent.
Oberhauser, Clara,Harms, Vanessa,Seidel, Katja,Schr?der, Benjamin,Ekramzadeh, Kimia,Beutel, Sascha,Winkler, Sven,Lauterbach, Lukas,Dickschat, Jeroen S.,Kirschning, Andreas
supporting information
p. 11802 - 11806
(2018/09/10)

Potassium fluoride on alumina: One-pot synthesis of S-allyl-S-methyldithiocarbonates by tandem condensation-alkylation-sigmatropic rearrangement
Allyl alcohols adsorbed on Al2O3-KF at room temperature reacted wit carbon disulfide and iodomethane and gave S-allyl-S-methyldithiocarbonate. Linalool did not give a rearrangement product. With chrysanthemyl alcohol, opening of the cyclopropane ring was observed.
Villemin,Hachemi
p. 2311 - 2318
(2007/10/02)

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Chemical Properties

Boiling Point: 126.1 °C at 760mmHg
Flash Point:45.7 °C
Density: 0.862 g/cm³
Storage Temp.:Freezer
Vapor Pressure: 14.4mmHg at 25°C
Refractive Index: 1.468
PKA: 10.18±0.25(Predicted)
PSA: 38.80000
LogP: 1.88240

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