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539-52-6

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Characteristic flavor formation of thermally processed N-(1-deoxy-α-D-ribulos-1-yl)-glycine: Decisive role of additional amino acids and promotional effect of glyoxal
The role of amino acids and α-dicarbonyls in the flavor formation of Amadori rearrangement product (ARP) during thermal processing was investigated. Comparisons of the volatile compounds and their concentrations when N-(1-deoxy-α-D-ribulos-1-yl)-glycine r
Zhan, Huan,Cui, Heping,Yu, Junhe,Hayat, Khizar,Wu, Xian,Zhang, Xiaoming,Ho, Chi-Tang
(2021/09/28)

Selective Alkylation and Allylation of Allylic Halides by Tetraorganoidates: Regio- and Stereo-selective Synthesis of Rosefuran and Sesquirosefuran
Tetraalkylindanes regioselectively alkylate allylic bromides at the α-carbon.In this way, 1,5-dienes have been regio- and stereo-selectively synthesized by the allyl-allyl coupling of allylic bromides and allylic indates, including rosefuran 1 and sequirosefuran 3.
Araki, Shuki,Jin, Shun-Ji,Butsugan, Yasuo
p. 549 - 552
(2007/10/02)

REGIO-CONTROLLED PRENYLATION AND GERANYLATION OF 3-FURYLMETHYLMAGNESIUM BROMIDE. SELECTIVE SYNTHESES OF 3-SUBSTITUTED FURANOID AND 2-SUBSTITUTED 3-METHYLFURANOID TERPENES.
Coupling reactions of 3-furylmethylmagnesium bromide with prenyl and geranyl diethyl phosphates gave 2-substituted 3-methylfurans, rosefuran and sesquirosefuran, as the main products. When the reactions were carried out in the presence of a catalytic amount of copper(I) iodide, normal coupling occurred and 3-substituted furans, perillene and dendrolasin, were formed in good yields. The related naturally occurring 3-substituted thiophene, 3-(4-methyl-3-pentenyl)thiophene, was also synthesized from 3-thienylmethylmagnesium bromide and prenyl diethy phosphate.
Araki,Butsugan
p. 1446 - 1449
(2007/10/02)

Formation of Dendrolasin, Sesquirosefuran, Perillene and Rosefuran by Biomimetic Autooxidation
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Tada, Masahiro,Chiba, Kazuhiro,Hashizume, Takeshi
p. 819 - 820
(2007/10/02)

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Chemical Properties

Boiling Point: 185.5°Cat760mmHg
Flash Point:55.9°C
Density: 0.913g/cm³
Vapor Pressure: 0.953mmHg at 25°C
Refractive Index: 1.47053 (589.3 nm, 21℃)
PSA: 13.14000
LogP: 3.17840

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