Asymmetric dihydroxylation of disubstituted allenes
Asymmetric dihydroxylation of 1,1-disubstituted and 1,3-disubstituted allenes can be used to synthesize chiral α-hydroxy ketones. We have also obtained α,α′-dihydroxy ketones with high enantioselectivity from 1,3-disubstituted allenes. Low conversion of the dihydroxylation of chiral allenes can be used as a kinetic resolution of sterically hindered allenes.
Fleming, Steven A.,Liu, Renmao,Redd, J. Ty
p. 8095 - 8098
(2007/10/03)
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