On the Mechanism of the Lewis Acid Mediated Cleavage of Chiral Acetals
The TiCl4-promoted cleavage of acetals has been shown to proceed by different mechanisms depending on the structure of the acetal, making it difficult to draw firm conclusions about the mechanism of related acetals based on model studies.
Sammakia, Tarek,Smith, Randall S.
p. 2997 - 3000
(2007/10/02)
1,3-dioxane derivatives, method of their synthesis and anti-peptic ulcer agent
A series of new 1,3-dioxane derivatives are disclosed. These compounds have an outstanding anti-peptic ulcerative activity and are useful as novel anti-peptic ulcer agents. Such compounds are synthesized by reacting a 1,3-butanediol derivative with suitable ketone.
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(2008/06/13)
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