The reaction of cyclic allylic alcohols with aliphatic alcohols in the presence of cerium(III) chloride
Cyclic secondary and tertiary allylic alcohols react with primary aliphatic alcohols in the presence of cerium(III) chloride heptahydrate to give alkyl allylic ethers. When secondary or tertiary aliphatic alcohols are used 1,3-dienes are obtained from allylic alcohols heaving the 3-methyl-2-en-1-ol moiety (3-8, 13-15).
Uzarewicz,Dresler
p. 181 - 195
(2007/10/03)
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