cas 5561-99-9, cis-11-Eicosenoic acid | Articles data ｜lookchem

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5561-99-9

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Three new fatty acid esters from the mushroom Boletus pseudocalopus
A bioassay-guided fractionation and chemical investigation of a MeOH extract of the Korean wild mushroom Boletus pseudocalopus resulted in the identification of three new fatty acid esters, named calopusins A-C (1-3), along with two known fatty acid methyl esters (4-5). These new compounds are structurally unique fatty acid esters with a 2,3-butanediol moiety. Their structures were elucidated through 1D- and 2D-NMR spectroscopic data and GC-MS analysis as well as a modified Mosher's method. The new compounds 1-3 showed significant inhibitory activity against the proliferation of the tested cancer cell lines with IC50 values in the range 2.77-12.51 μM. AOCS 2011.
Kim, Ki Hyun,Choi, Sang Un,Lee, Kang Ro
experimental part
p. 593 - 599
(2012/09/10)

Pheromones via organoboranes: Part IV - Synthesis of (Z)-9-tricosene (Muscalure)
Synthesis of (Z)-9-tricosene (muscalure) (9) is reported starting from oleyl alcohol by two carbon homologation via dianion of phenoxyacetic acid followed by reduction (LAH), oxidation (PCC) and Grignard reaction.
Dhillon, Ranjit S.,Singh, Rupinder P.,Singh, Jasvinder
p. 718 - 721
(2007/10/03)

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Chemical Properties

Appearance/Colour :yellowish paste
Melting Point: 25 - 32 C
Boiling Point: 426.3oC at 760 mmHg
Flash Point:110 ºC
Density: 0.883
Solubility:Chloroform (Slightly), DMSO (Slightly)
Storage Temp.:−20°C
Vapor Pressure: 1.84E-08mmHg at 25°C
Refractive Index: n20/D 1.4606(lit.)
PKA: 4.78±0.10(Predicted)
BRN: 1727313
PSA: 37.30000
LogP: 6.88870

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