Branched-Chain Carbohydrate Lactones from a Samarium(II) Iodide-Promoted Serial Deoxygenation-Carbonyl Addition Reaction
A new deoxygenation-carbonyl addition reaction mediated by samarium(II) iodide (SmI2) in THF/HMPA was examined with carbohydrate lactones and several substrates containing an α-alkoxy carboxylic ester.In a single reaction, these compounds were deoxygenate
Enholm, Eric J.,Jiang, Shujun,Abboud, Khalil
p. 4061 - 4069
(2007/10/02)
BRANCHED CHAIN CARBOHYDRATE LACTONES FROM A TANDEM SmI2 DEHYDROGENATION-CARBONYL ADDITION REACTION
Treatment of a carbohydrate lactone with a ketone in the presence of SmI2-HMPA produces a deoxygenation/carbonyl addition reaction to afford new C2-branched chain carbohydrates.
Enholm, Eric J.,Jiang, Shujun
p. 2247 - 2252
(2007/10/02)
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