Reactivity of heterocyclic α-aminomethylsilanes with alcohols
[Figure not available: see fulltext.] Alkoxylation of N-substituted heterocyclic aminomethylsilyl moieties was studied using primary and tertiary alcohols. The reaction of 4-(silylmethyl)morpholine and 1-(silylmethyl)azepane under catalyst- and solvent-free conditions leads to the formation of dialkoxy- and trialkoxyaminomethylsilyl derivatives. The methanolysis of 4-(silylmethyl)morpholine resulted in trimethoxyaminomethylsilane formation as the main product and two byproducts, i.e., tetramethoxysilane and N-methylmorpholine.
Pypowski, Krzysztof,Mojzych, Mariusz
p. 320 - 324
(2021/03/31)
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