Oxidation of monohydric and dihydric alcohols with CCl4 catalyzed by molybdenum compounds
Mo(CO)6 catalyzed oxidation of alcohols and diols with tetrachloromethane. Primary oxidation products in reaction of alcohols with CCl4 are alkyl hypochlorites, and final products depending on the structure of initial alcohol are aldehydes (as acetals), ketones, chloroketones, and esters.
Reactions du n=chloroparatoluenesulfonamidate de sodium (chloramine t) sur les olefines en miliu acide organique
Vic. chloro-acetoxy and vic. chloro-tosylamino alcanes are the main products of the electrophilic reaction of chloramine T on olefins in acetic acid. The stereochemistry of the acetoxy chloration of the 2-butenes and cyclohexene is trans.