- Photocatalytic degradation of polycyclic aromatic hydrocarbons in GaN:ZnO solid solution-assisted process: Direct hole oxidation mechanism
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GaN:ZnO exhibits excellent activity for the photodegradation of PAHs, and the activity can be obviously improved by loading Pt. The degradation of PAHs in the system of GaN:ZnO is induced by the formation of holes. The holes generated then interact with PAHs to produce PAHs+, which is active enough to react with O2.
- Kou, Jiahui,Li, Zhaosheng,Guo, Yong,Gao, Jun,Yang, Ming,Zou, Zhigang
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experimental part
p. 48 - 54
(2010/10/01)
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- Chromium(VI) Based Oxidants; II. Zinc Dichromete Trihydrate: A Versatile and Mild Reagent for the Oxidation of Organic Compounds
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Zinc dichromate trihydrate is an easily prepared, stable, and cheap reagent for the efficient oxidation of organic compounds in aprotic solvents at room temperature.
- Firouzabadi, H.,Sardarian, A. R.,Moosavipour, H.,Afshari, G. M.
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p. 285 - 288
(2007/10/02)
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- OXYGENATION OF AROMATIC AND ALIPHATIC HYDROCARBONS BY A NEW REAGENT SYSTEM, Fe(CH3CN)6(2+)-H2O2-Ac2O: AN EFFECTIVE MODEL REAGENT FOR MONO-OXYGENASE
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Reactions of aromatic and aliphatic hydrocarbons with a new system, Fe(CH3CN)6(2+) - H2O2 - Ac2O in CH3CN, gave oxygenation products with fairly high reaction efficiency ( Tables I and II )compared to known to reagent systems used as enzyme models for mono-oxygenases.Investigations of the mechanism of these reactions indicated the involvement of either complex C.FeIV(OH)(OAc)(2+), or complex D, FeIV(OAc)(2+), dependig on the organic substrate.Keywords-oxygenation; aromatic hydrocarbon; aliphatic hydrocarbon; hexakisacetonitrile iron(II) perchlorate; hydrogen peroxide; enzyme model; mono-oxygenase
- Kotani, Eiichi,Kobayashi. Shigeki,Ishii, Yoko,Tobinaga, Seisho
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p. 4671 - 4679
(2007/10/02)
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- ATTEMPTS TO PREPARE AROMATIC O-ACYL-HYDROXYLAMINES-III0
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From the reaction mixture of the dehydrobromination of 1-bromo-4-benzoyloxyimino-1,2,3,4-tetrahydrophenanthrene (1) with 1,8-diazabicycloundec-7ene (DBU) in benzene and in heavy atom solvents several products were isolated and their structures eluc
- Juneja, T. R.,Garg, D. K.,Schaefer, W.
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p. 551 - 556
(2007/10/02)
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