AROMATIC FLUORINE DERIVATIVES. XCIX. REACTION OF OCTEFLUORONAPTHALENE WITH PENTAFLUOROBENZENESULFONYL HALIDES AND DI-tert-BUTYL PEROXIDE
In the reaction of octafluoronapthalene with oxygen-containing radicals (pentaflurophenylsulfonyl and tert-butoxyl) the stabilization of the radical ? complexes is realized by the formation of the heptafluoronapthoxyl radical, the subsequent transformations of which lead to polyfluorinated derivatives of oxodihydronapthalenes.The products from homolytic substitution and the products from dimerization of the respective radical ? complexes are formed in the reaction of octafluoronapthalene with methyl and pentafluorophenyl radicals.Analysis of the 19F NMR spectra of the obtained dimeric product makes it possible to suppose that a rearrangement with 1,2-migration of a fluorine atom occurs in the ? complexes from the addition of the methyl and pentafluorophenyl radicals to octafluoronapthalene.
Bogachev, A. A.,Kobrina, L. S.,Yakobson, G. G.
p. 967 - 975
(2007/10/02)
ACTION OF ELECTROPHILIC AGENTS ON POLYFLUORINATED AROMATIC COMPOUNDS. XVI. REACTION OF POLYFLUORINATED NAPHTHALENES AND DIHYDRONAPHTHALENES WITH PENTAFLUOROBENZENE IN ANTIMONY PENTAFLUORIDE
The reaction of 2-X-heptafluoronaphthalenes (X=F, H, CH3) with pentafluorobenzene in antimony pentafluoride leads to formation of 3-X-undecafluoro-1-phenylnaphthalenes and 3-X-pentadecafluoro-1,5-diphenylnaphthalenes.On the basis of the realized orientati
Selivanov, B. A.,Pozdnyakovich, Yu. V.,Chuikova, T. V.,Osina, O. I.,Shteingarts, V. D.
p. 1626 - 1639
(2007/10/02)
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