- Synthesis and pyrolysis of tetrahydro-1,4-oxazine-3,5-diones and tetrahydro-1,4-thiazine-3,5-diones
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The preparation and characterization of six 4-substituted tetrahydro-l,4-oxazine-3,5-diones and five 4-substituted tetrahydro-l,4-thiazine-3,5-diones is described. Upon flash vacuum pyrolysis at 700°C these give N-substituted acetamides and nitriles, and a mechanism for formation of these products is proposed.
- Aitken,Farrell,Kirton
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p. 1526 - 1531
(2007/10/03)
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- GIF OXIDATION OF SOME ALICYCLIC AMINES
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The Gif oxidation of seven alicyclic tertiary amines leads essentially to the formation of lactams.The structure of the products present in trace amounts supports the mechanistic hypothesis previously advanced.The structures of the oxidation products were investigated using high performance GC-MS system.
- Boivin, J.,Gaudin, D.,Labrecque, D.,Jankowski, K.
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p. 2281 - 2282
(2007/10/02)
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