- Synthesis and properties of chromophore-functionalized monovinylsilsesquioxane derivatives
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A facile and efficient Pd-based Suzuki-Miyaura coupling reaction leading to mixed chromophores with styryl fragments, enabling their further application, is presented. We also disclose their use in the formation of monofunctionalized silsesquioxanes with a chromophore group covalently bound to a T8 core that have been prepared via a cross-metathesis reaction. These new materials were studied in terms of their photophysical and also thermal properties.
- ?ak, Patrycja,Bo?t, Ma?gorzata,Dudziec, Beata,Grzelak, Magdalena,Januszewski, Rafa?,Marciniak, Bronislaw,Marciniec, Bogdan,Rachuta, Karolina
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supporting information
p. 7659 - 7664
(2020/06/09)
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- Copper-catalyzed arylation of polycyclic aromatic hydrocarbons by the PO group
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The first example of a directed and regioselective arylation of polycyclic aromatic hydrocarbons (PAHs) by using a PO directing group is reported herein. The protocol uses a cheap copper catalyst, and results in a breakthrough meta-selective C-H functionalization of arylphosphine oxide compounds. Substrates with potential fluorescence properties, for example, pyrene and fluoranthene, were successfully arylated under the system, thus achieving an efficient modification of fluorescent molecules containing the PO functional group. This journal is
- Niu, Yuan,Qi, Zhichao,Lou, Qinxin,Bai, Pengbo,Yang, Shangdong
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supporting information
p. 14721 - 14724
(2020/12/02)
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- NOVEL COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
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Organic electroluminescent devices with lowered driving voltages, and enhanced efficiencies and lifetimes are provided.
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Paragraph 0110-0111; 0115-0116
(2020/05/29)
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- ORGANIC ELECTROLUMINESCENT ELEMENT AND MONOAMINE COMPOUND FOR ORGANIC ELECTROLUMINESCENT ELEMENT
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PROBLEM TO BE SOLVED: To provide an organic electroluminescent element with high efficiency and an amine compound therefor. SOLUTION: The amine compound for organic electroluminescent element is a monoamine compound expressed by the compound, the compound
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Paragraph 0123; 0124; 0125; 0126; 0133; 0134-0136
(2019/09/05)
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- Annular N-heterocycle double-carbene palladium coordination compound and preparation method and application thereof
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The invention discloses an annular N-heterocycle double-carbene palladium coordination compound and a preparation method and application thereof. 1,4-2(N-ethyl-benzimidazole onium methyl)-2,3,5,6-tetramethylbenzene arene salt is used as a precursor of the annular N-heterocycle double-carbene palladium coordination compound. The synthetic annular N-heterocycle double-carbene palladium coordinationcompound is used as a catalyst and used for catalyzing the cross-coupling reaction of carbon-carbon bonds. The preparation method of the annular N-heterocycle double-carbene palladium coordination compound comprises the steps that under nitrogen protection, 1,4-2(N-ethyl-benzimidazole onium methyl)-2,3,5,6-tetramethylbenzene arene salt and metal compounds are added to a reaction vessel according to a molar ratio of 1:(2-5), an organic solvent is added to the mixture, then reaction is conducted for 12-24 hours under the temperature of 0-100 DEG C, the mixture is filtered and subjected to etherdiffusion, and the annular N-heterocycle double-carbene palladium coordination compound is obtained. The prepared annular N-heterocycle double-carbene palladium coordination compound is mainly appliedto the technical field of catalysts.
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Paragraph 0036; 0037; 0038; 0039; 0040; 0041
(2018/04/26)
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- Synthesis of Positional Isomeric Phenylphenalenones
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A series of isomeric phenylphenalenones in which the phenyl ring is located at all possible peripheral positions of the phenalenone nuclei was synthesized. The structural characteristics of the series, in which topological variation is permitted with minimal electronic disturbance, could, in principle, allow for easy pharmacophore recognition when the compounds are aligned in steroidomimetic conformations.
- Ospina, Felipe,Ramirez, Adrian,Cano, Marisol,Hidalgo, William,Schneider, Bernd,Otálvaro, Felipe
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p. 3873 - 3879
(2017/04/11)
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- A kind of organic compound and its use this organic compound electroluminescent device
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The invention relates to an organic compound. The organic compound has a structure represented in a formula I, wherein R1, R2 and R3 are independently selected from hydrogen atom, substituted or non-substituted C1-C30 alkyl, substituted or non-substituted C1-C30 naphthenic base, substituted or non-substituted C1-C30 alkoxy, substituted or non-substituted C6-C30 aryl, substituted or non-substituted C6-C30 aryloxy, substituted or non-substituted C6-C30 arylamine, substituted or non-substituted C2-C30 heterocyclic ring, substituted or non-substituted C6-C30 condensed polycyclic group, hydroxyl, cyano group and substituted or non-substituted amino, respectively. Furthermore, the invention relates to an electroluminescent device, wherein the electroluminescent device comprises a hole injection layer and/or a hole transport layer using at least one of the compounds.
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Paragraph 0054-0056;0057
(2016/10/08)
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- An electroluminescent compound and an electroluminescent device comprising the same
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The present invention relates to an organic light emitting compound applied to an organic light emitting device. The organic light emitting compound is represented by the chemical formula 1 to chemical formula 3 and has one or more substituents represented by the structural formula 1 or structural formula 2. An organic light emitting device having excellent light emitting properties such as driving voltage, luminance, long life, etc. can be made if the organic light emitting compound is applied as a host compound or a dopant compound in a luminous layer.COPYRIGHT KIPO 2016
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Paragraph 0145; 0445; 0446; 0447; 0448
(2016/11/24)
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- An electroluminescent compound and an electroluminescent device comprising the same
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The present invention relates to an organic light-emitting compound applied to an organic electroluminescent device, represented by chemical Formula 1, and having one or more substituents represented by structural formula 1 or structural formula 2. When the organic light-emitting compound is applied as a host compound or a dopant compound in a light-emitting layer, an organic electroluminescent device having excellent light-emitting properties such as a driving voltage, brilliance, and long lifecycle may be obtained.COPYRIGHT KIPO 2016
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Paragraph 0112; 0131-0133; 0251-0253
(2016/12/01)
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- An electroluminescent compound and an electroluminescent device comprising the same
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The present invention relates to an organic light emitting compound applied to an organic light emitting device. The organic light emitting compound: is represented by chemical formula 1; includes one or more substituted bodies represented by structural formula 1 or structural formula 2; and is capable of realizing an organic light emitting device having excellent luminous properties such as driving voltage, luminance, a long life and the like in the case of being applied as a phosphorescent host compound in a hole transporting functional layer or an emissive layer.COPYRIGHT KIPO 2016
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Paragraph 0234; 0235; 0960; 0961
(2016/10/07)
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- Synthesis of precursors for large-diameter hemispherical buckybowls and precursors for short carbon nanotubes
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We report herein the synthesis of six precursor molecules for the rational synthesis of isomerically pure armchair, zigzag, or chiral single-walled carbon nanotubes (SWCNTs). The polycyclic aromatic hydrocarbons possess the required carbon connectivity for the generation of extended hemispherical buckybowls with predefined geometry through intramolecular cyclodehydrogenation. The precursors for the short carbon nanotubes and the large-diameter hemispherical buckybowls have potential for the rational initiation of single-chirality SWCNT growth on metal surfaces. The options for the construction of precursors for various SWCNT chiralities based on the suggested synthesis strategy are presented.
- Mueller, Andreas,Amsharov, Konstantin Yu.
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p. 6155 - 6164,10
(2020/09/16)
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- NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
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Provided are novel organic electroluminescent compounds and an organic electroluminescent device using the same. Because the organic electroluminescent device using the organic electroluminescent compound as a hole transport material or a hole injection material exhibits good luminous efficiency and excellent lifetime properties, it is used to manufacture OLED devices having superior operating lifetime and consuming less power due to improved power efficiency.
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Page/Page column 16-17
(2012/02/13)
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- NAPHTHALENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE, AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
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A naphthalene derivative represented by the following formula (1) is provided. In the formula, Ar1 to Ar4 each represent an aromatic hydrocarbon cyclic group having 6 to 18 carbon atoms forming a ring. The aromatic hydrocarbon cyclic group has none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. n, m and 1 each represent an integer in a range of 1 to 5. p represents an integer in a range of o to 5. When n, m, 1 and p each are 2 or more, a plurality of Ar1 to Ar4 may be mutually the same or different.
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- AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
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Provided are a novel aromatic amine derivative represented by the following general formula (1) and an organic electroluminescent device including an organic thin film formed of one or a plurality of layers including at least a light emitting layer interposed between a cathode and an anode, in which at least one layer of the organic thin film contains the aromatic amine derivative alone or as a component of a mixture, which contributes to suppressing molecular crystallization and improving yield in the production of an organic electroluminescent device, whereby an organic electroluminescent device having a long lifetime can be obtained, and the aromatic amine derivative is capable of realizing the organic electroluminescent device: where: R1 represents an aryl group or the like; a represents an integer of 0 to 4; b represents an integer of 1 to 3; and at least one of Ar1 to Ar4 represents a group represented by the following general formula (2): where Ar5 represents a fused aromatic ring group and Ar6 represents an aryl group or an aromatic heterocyclic group, where remaining groups of Ar1 to Ar4, none of which is represented by the general formula (2), each independently represent an aryl group or an aromatic heterocyclic group.
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Page/Page column 26
(2009/01/20)
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- ANTHRYLARYLENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE, AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
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Disclosed is an anthrylarylene derivative having a specific structure. Also disclosed is an organic electroluminescent device wherein an organic thin film composed of one or more layers including at least a light-emitting layer is interposed between a cathode and an anode, and at least one layer in the organic thin film contains the anthrylarylene derivative by itself or as a component of a mixture. Such an organic electroluminescent device has high luminous efficiency and long life. Further disclosed is an anthrylarylene derivative having an adequate glass transition temperature which is particularly suitable as a light-emitting material to be used in the above-described organic EL device.
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Page/Page column 49
(2008/06/13)
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- AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
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Disclosed is an organic electroluminescent device wherein an organic thin film which is composed of one or more layers including at least a light-emitting layer is interposed between a cathode and an anode. Since at least one layer of the organic thin film contains a novel aromatic amine derivative, which has an asymmetric structure wherein two different amine units are bonded through a linking group, by itself or as a component of a mixture, molecules are hardly crystallized, thereby improving the production yield of the organic electroluminescent device. This organic electroluminescent device has a long life.
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Page/Page column 66
(2008/06/13)
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