Selenium-promoted synthesis of enantiomerically pure substituted morpholines starting from alkenes and chiral aminoalcohols
Enantiomerically pure 2,3,5-trisubstituted morpholines with two newly created stereocenters have been prepared by a short synthetic sequence having as the key step the selenium-promoted addition of (R)-phenylglycinol to a substituted alkene.
Tiecco, Marcello,Testaferri, Lorenzo,Marini, Francesca,Sternativo, Silvia,Santi, Claudio,Bagnoli, Luana,Temperini, Andrea
p. 2651 - 2657
(2007/10/03)
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