Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols
Equation presented. A mild and general palladium-catalyzed insertion of 1,2-diethoxy-1,1,2,2-tetramethyldisilane into a variety of aryl bromides affords the aryldimethylsilyl ethers in high yields. Hydrolysis of the ethers under pH-optimized conditions results in the exclusive formation of the desired aryldimethylsilanols.
Denmark, Scott E.,Kallemeyn, Jeffrey M.
p. 3483 - 3486
(2007/10/03)
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