- Synthesis of Amino Alcohols of the Cyclododecane and Decahydro-1,4-ethanonaphthalene Series
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Abstract: 2-Aminocyclododecan-1-ol and 6(3)-aminodecahydro-1,4-ethanonaphthalen-5(2)-ols (mixture of isomers) were synthesized in two steps via oxidative hydroxybromination of cyclododecene and 1,2,3,4,4a,5,6,8a(1,4,4a,5,6,7,8,8a)-octahydro-1,4-ethanonaph
- Alimardanov, H. M.,Babayev, N. R.,Ismailova, Sh. I.,Sadigov, O. A.
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- Switching the reaction pathways of electrochemically generated β-haloalkoxysulfonium ions - Synthesis of halohydrins and epoxides
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β-Haloalkoxysulfonium ions generated by the reaction of electrogenerated Br+ and I+ ions stabilized by dimethyl sulfoxide (DMSO) reacted with sodium hydroxide and sodium methoxide to give the corresponding halohydrins and epoxides, respectively, whereas the treatment with triethylamine gave α-halocarbonyl compounds.
- Shimizu, Akihiro,Hayashi, Ryutaro,Ashikari, Yosuke,Nokami, Toshiki,Yoshida, Jun-Ichi
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p. 242 - 248
(2015/06/01)
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