Perfluoroalkylation of heterocumulenes with trimethyl(perfluoroalkyl)silanes in the presence of fluoride ions: Synthesis of perfluoroalkanesulfinyl amides from N-organylsulfinyl amines
Trimethyl(perfluoroalkyl)silanes react in the presence of fluoride ions with N-organylsulfinylamines under mild conditions to give the corresponding perfluoroalkanesulfinyl amides in high yields.