Ozonides of Substituted Norbornenes with Exo- and Endo-Positioned Peroxide Bonds
Ozonolyses of three methyl-substituted norbornenes 1a-c on polyethylene gave in each case the corresponding ozonide 2 with an endo-positioned peroxide bridge.From 1b, ozonide 3b with an exo-positioned peroxide bridge was obtained, too.Thermally and photolytically induced decompositions of the ozonides are described.
Griesbaum, Karl,Krieger-Beck, Petra,Beck, Johannes