The packing for use in resolution proposed for the liquid chromatography for particularly the opti-cal resolution of racemic compounds is prepared by reacting a silica gel carrier with a so-called silane treating agent to introduce a spacer part therein and chemically bonding it with a copper salt of a carboxylic or thiocarboxylic acid selected from the group consisting of optically active D- and L-2--acetizinecaroxylic acid, proline, hydroxyproline and allohydroxyproline. The steric bulkiness, the distance between the silica gel and the optically active group and the degree of hydrophobicity are specified so as to obtain an excellent resolving power.
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(2008/06/13)
Method for preparing 2-chloroethylsilanes
A method for preparing 2-chloroethylsilanes which comprises reacting a vinylchlorosilane with hydrogen chloride in the presence of a catalyst consisting of at least one organoaluminum compound, or the product obtained from the in situ reaction of such an aluminum compound with at least one of the reactants. The catalyst may first be deactivated, if desired, by the addition of a liquid organopolysiloxane to the reaction mixture, prior to the distillation of the 2-chloroethylsilane.
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(2008/06/13)
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