Driving force for oxygen-atom transfer by heme-thiolate enzymes
Absolutely: Redox potentials for three redox couples in AaeAPO-catalyzed reactions have been measured, thus placing these heme-thiolate reactive intermediates on an absolute energy scale for the first time. The importance of the axial thiolate ligand and
Wang, Xiaoshi,Peter, Sebastian,Ullrich, René,Hofrichter, Martin,Groves, John T.