Intermolecular SNAr of the heterocycle-activated nitro and fluoro groups-application in the synthesis of polyazamacrocyclic ligands
A new class of tetracylic benzimidazole compounds and derivatives thereof. Additionally provided is a synthetic route for the generation of these and related compounds via Intramolecular Aromatic Nucleophilic Substitution (SNAr) of the Benzimid
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Page/Page column 17
(2010/02/14)
Intramolecular Aromatic Nucleophilic Substitution of the Benzimidazole-Activated Nitro Group
(Equation Presented) A wide range of 2-(2-nitrophenyl)-1H-benzimidazoles undergo high-yielding intramolecular SNAr of nitrite with N-pendant alkoxides under mild conditions (DMF, rt). When this operationally simple process is carried out at ele
Fekner, Tomasz,Gallucci, Judith,Chan, Michael K.
p. 4795 - 4798
(2007/10/03)
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