- Safe and Convenient Synthesis of Primary N -Nitramines in the Freon Media
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A convenient one-pot synthesis of primary aliphatic N-nitramines, which includes the nitration of available N,N′-dialkyloxalamides or N-alkylcarbamates with dinitrogen pentoxide in the 1,1,1,2-tetrafluoroethane media followed by ammonolysis of intermediate N-nitroamides in the same solvent has been developed. The method is environmentally safe, and affords target N-nitramines in up to 94% overall yield.
- Zharkov, Mikhail N.,Kuchurov, Ilya V.,Fomenkov, Igor V.,Tartakovsky, Vladimir A.,Fedyanin, Ivan V.,Zlotin, Sergei G.
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supporting information
p. 1103 - 1108
(2017/02/24)
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- A Novel Synthesis of β-Aminoalkylnitroamines. rac-β-Nitroaminoalanine and N-Nitroethylenediamine, Two Repoted Metabolites from Agaricus silvaticus
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N-Nitroethylenediamine and rac-β-nitroaminoalanine have been prepared in good yields by the same general method, involving addition of methyl N-nitrocarbamate to aziridine or ethyl aziridine-2-carboxylate, respectively.Additive 13C NMR shift parameters for the nitroamino group have been estimated.
- Nilsson, Liselott,Noori, Ghazi,Bergman, Rolf,Kesler, Ewa,Sterner, Olov,Wickberg, Boerje
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p. 929 - 934
(2007/10/02)
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